马念,曾胜,胡涛,龚兴厚,胡珍,吴崇刚.聚对苯二甲酸乙二醇酯的结晶成核改性研究进展[J].材料导报,2016,30(13):1-9, 22
聚对苯二甲酸乙二醇酯的结晶成核改性研究进展
Enhancing the Crystalline Nucleation of Poly(ethylene terephthalate):A State-of-the-art Review
 
DOI：10.11896/j.issn.1005-023X.2016.013.001

中文关键词: 聚对苯二甲酸乙二醇酯 结晶 异相成核 离子簇集诱导成核 改性

英文关键词: poly(ethylene terephthalate), crystallization, heterogeneous nucleation, ion-aggregation induced nucleation, modification

基金项目:
作者 单位
马念
湖北工业大学绿色轻工材料湖北省重点实验室,武汉 430068;绿色轻质材料与加工湖北工业大学协同创新中心,武汉 430068;湖北工业大学材料科学与工程学院,武汉 430068

曾胜
湖北工业大学材料科学与工程学院,武汉 430068

胡涛
湖北工业大学绿色轻工材料湖北省重点实验室,武汉 430068;绿色轻质材料与加工湖北工业大学协同创新中心,武汉 430068;湖北工业大学材料科学与工程学院,武汉 430068

龚兴厚
湖北工业大学绿色轻工材料湖北省重点实验室,武汉 430068;绿色轻质材料与加工湖北工业大学协同创新中心,武汉 430068;湖北工业大学材料科学与工程学院,武汉 430068

胡珍
湖北工业大学材料科学与工程学院,武汉 430068

吴崇刚
湖北工业大学绿色轻工材料湖北省重点实验室,武汉 430068;绿色轻质材料与加工湖北工业大学协同创新中心,武汉 430068;湖北工业大学材料科学与工程学院,武汉 430068

中文摘要:
      聚对苯二甲酸乙二醇酯(PET)因其重复结构单元中含有刚性苯环而成核慢、结晶度低,从而导致综合力学性能与耐热性较差,限制了其工程化应用,故对PET进行成核改性以提高结晶速率与结晶度成为亟待解决的问题。综述了PET的4大类成核剂:无机填料、有机小分子、有机高分子及复合型成核剂；在此基础上,提出机理上不同于异相成核的“离子簇集诱导成核”的概念,即与离子共价相连的聚合物链段因离子簇集而在离子簇近围紧密堆砌,从而诱导“拥挤”链段结晶成核。无机填料类成核剂包括粘土、氧化物与氢氧化物、无机盐、Si3N4及碳纳米管/石墨等,其成核机理均为异相成核。有机小分子类成核剂涉及羧酸盐、二胺、双酰胺及改性山梨醇等,其中羧酸盐成核机理为离子簇集诱导成核,而其它均属于异相成核。有机高分子类成核剂分为结晶性聚合物、液晶高分子、嵌段共聚物及离子交联型聚合物等；其中前三者属异相成核,后者为离子簇集诱导成核。复合型成核剂为两种以上成核剂(或成核机理)配合使用协同促进PET结晶成核。对比发现,有机高分子与复合型成核剂效果较好,且不会引起PET的降解,为PET优良成核剂。异相与离子簇集诱导耦合高分子成核剂为PET结晶成核改性未来的重点发展方向之一。
英文摘要:
      Owing to the inclusion of a rigid phenylene group in its constitutional repeating unit, poly(ethylene terephthalate) (PET) is of slow nucleation and thus low degree of crystallinity, which results in relatively deteriorated overall mechanical properties as well as poor heat resistance that limit its engineering applications. Therefore, it is imperative that the nucleation of PET be so modified as to improve its crystallization rate and degree of crystallinity. Herein, the four types of nucleating agents reported in the literatures for PET crystallization have been reviewed, i.e., inorganic fillers (IFs), organic small-molecules (OSMs), organic polymers (OPs), and composite nucleating agents (CNAs), on the basis of which a concept of “ion-aggregation induced nucleation” (IAIN) different in mechanism from heterogeneous nucleation (HN) has been proposed, that is the polymer chain-segments covalently attached to ion pairs, upon ion aggregation, are closely packed in the coronas of the ionic aggregates, which induces crystalline nucleation of the “crowding” chain segments. The IF nucleating agents include clays, oxides and hydroxides, mineral salts, Si3N4, carbon nanotubes/graphite, etc, all of which assume the HN mechanism. The OSM nucleating agents involve carboxylate salts, diamines, bisamides, modified sorbitols, etc, among which carboxylate salts belong to the IAIN mechanism while all others the HN. Crystalline polymers, liquid-crystalline polymers, block copolymers, ionomers, etc, constitute the OP nucleating agents of PET, where the former three are of the HN mechanism while the latter the IAIN. The CNAs comprise two or above nucleating agents or mechanisms that synergistically promote the crystalline nucleation of PET. By comparison, the OPs and CNAs are excellent nucleating agents for PET in that they have the best nucleation effectiveness and at the same time do not give rise to PET-degradation. HN and IAIN coupled OP nucleating agents are one of the most important and promising R&D approaches to the effective modification of PET crystalline nucleation.

汪荣亮,谷德健,刘全俊.纳米孔传感技术应用于肿瘤早期诊断的研究进展[J].材料导报,2016,30(13):10-16
纳米孔传感技术应用于肿瘤早期诊断的研究进展
Progress in Nanopores-based Sensing Technology for Tumor Early Diagnosis
 
DOI：10.11896/j.issn.1005-023X.2016.013.002

中文关键词: 纳米孔 肿瘤 早期诊断 肿瘤标志物

英文关键词: nanopore, tumor, farly diagonosis, tumor marker

基金项目:国家自然科学基金(62372031；61071050)；中央高校基本科研业务费专项资金；江苏省博士后科研资助计划(1501018C)
作者 单位 E-mail
汪荣亮
东南大学生物科学与医学工程学院,南京 210096
101101115@seu.edu.cn

谷德健
东南大学生物科学与医学工程学院,南京 210096
 
刘全俊
东南大学生物科学与医学工程学院,南京 210096
101101115@seu.edu.cn

中文摘要:
      近几十年来,尽管研究人员一直在努力开发新的诊断和治疗技术,癌症仍然是世界上发病率和死亡率最高的疾病之一。其中关键点是在肿瘤发生的早期进行诊断。现有的肿瘤早期诊断方法有很多缺点,比如对病患肿瘤组织的侵入。因此,与肿瘤相关的无创诊断的研究已经越来越多并已经取得进展。研究发现,蛋白、DNA或者RNA等生物大分子都有可能成为潜在的肿瘤标志物,已有的检测方法也存在许多缺点。纳米孔因具有独特的物理和电学性质,对生物分子的检测有快速、无需标记和扩增等优点,已被广泛使用和证明。在不远的将来,应用纳米孔对肿瘤标志物进行检测,进行肿瘤诊断并监控治疗过程值得期待。主要介绍了纳米孔传感技术应用于肿瘤早期诊断中肿瘤标志物检测的研究进展。
英文摘要:
      Despite several decades of intensive effort to exploit new techniques for diagnosis and treatment, cancer is still one of the diseases with highest incidence and mortality in the world. The key is to diagnose tumors at early stages. Current early diagnosis methods have some deficiencies, such as invasiveness to tumor tissues of patients. Therefore, vast numbers of studies and developments in the non-invasive diagnostic methods have been conducted and many new biomarkers have been found to detect tumors at early stages. Proteins, DNA fragments, and RNA fragments may become potential cancer biomarkers while detection methods also have some shortcomings. Nanopores, with its unique physical and electrical properties, detect bio-molecules rapidly without labeling or amplification, and have been proven to be very useful in sensing. In the near future, it is highly anticipated that we might be able to detect tumors at a very early stage and monitor the treatment process using nanopores for non-invasive methods. The application of nanopore-based sensing technology for detection of tumor markers at tumors early stages is reviewed.

纪志永,孙步云,袁俊生,赵孟瑶,焦朋朋.锰基锂离子筛前体及其掺杂和表面修饰进展[J].材料导报,2016,30(13):17-22
锰基锂离子筛前体及其掺杂和表面修饰进展
Doping and Surface Modification of Lithium Manganese Oxides Used as Ion-sieve Precursor:A Review
 
DOI：10.11896/j.issn.1005-023X.2016.013.003

中文关键词: 锂离子筛 稳定性 掺杂 表面修饰

英文关键词: lithium ion-sieve, stability, doping, surface modification

基金项目:国家自然科学基金(20806019)；天津市应用基础及前沿技术研究计划资助项目(12JCQNJC03300)；长江学者和创新团队发展计划资助项目(PCSIRT;IRT14R14)
作者 单位 E-mail
纪志永
河北工业大学海洋科学与工程学院/海水资源高效利用化工技术教育部工程研究中心,天津 300130
jizhiyong@hebut.edu.cn

孙步云
河北工业大学海洋科学与工程学院/海水资源高效利用化工技术教育部工程研究中心,天津 300130
 
袁俊生
河北工业大学海洋科学与工程学院/海水资源高效利用化工技术教育部工程研究中心,天津 300130
jizhiyong@hebut.edu.cn

赵孟瑶
河北工业大学海洋科学与工程学院/海水资源高效利用化工技术教育部工程研究中心,天津 300130
 
焦朋朋
河北工业大学海洋科学与工程学院/海水资源高效利用化工技术教育部工程研究中心,天津 300130
 

中文摘要:
      锰基锂离子筛是一种极具发展前景的提锂吸附材料。对其晶体结构及影响其结构稳定性的因素进行了总结,重点讨论了阴离子、阳离子以及复合3种掺杂修饰和以包覆为主的表面修饰的研究概况；指出两类修饰可在一定程度上提高锰基锂离子筛的结构稳定性、抑制Jahn-Teller效应,进而降低Mn的溶损、提高循环应用的稳定性,但修饰未能从根本上解决离子筛提锂过程中溶损的关键问题,而且修饰元素的引入也为后续的分离带来新问题。最后,从以原子量低于锰的元素为掺杂对象和应用过程涉及的洗脱剂筛选两方面,对锰基锂离子筛的发展前景进行了展望。
英文摘要:
      Among varieties of adsorbents for extracting lithium from solution such as seawater, salt lake brine and geothermal water, spinel manganese oxides usually called lithium ion-sieve are the most promising ones. The crystal structure of spinel manganese oxides, and two factors (disproportionation reaction of Mn3+ and Jahn-Teller effect) correlating with the structure stability are summarized respectively. Doping (anion doping, cation doping and recombination doping) and surface modification (cladding, embedding and blending) are emphatically discussed in the way of enhancing the structure stability, inhibiting the Jahn-Teller effect and reducing the loss of Mn forming the skeleton of the ion-sieve. However, the loss of Mn is still known as an inhibiting factor which has not been solved through doping and surface modification at present. At the same time, the elements introduced in the doping and surface modification will bring some new trouble in the subsequent separation process. Finally, doping with less atomic weight element than Mn and application of green eluent for reducing the loss of Mn are proposed as the potential developing direction in future, and promising avenues of extraction lithium with manganese-based lithium ion-sieve are expected to meet the ever-increasing need of lithium.

贾永芳,蔡芳共,鲁双伟,杨峰,赵勇.双通TiO2纳米管阵列膜制备及应用研究[J].材料导报,2016,30(13):23-29, 54
双通TiO2纳米管阵列膜制备及应用研究
Research on the Preparation and Application of Through-hole TiO2 Nanotube Arrays Membranes
 
DOI：10.11896/j.issn.1005-023X.2016.013.004

中文关键词: TiO2纳米管阵列膜 双通 分离 制备 应用

英文关键词: TiO2 nanotube arrays, through-hole, separation, preparation, application

基金项目:国家自然科学基金(50872116)；教育部超导磁悬浮列车创新团队项目(IRT0751)；教育部博士点基金(SRDP200806130023)；中央高校基本科研业务费专项资金(2009QK46;SWJTU09ZT24)
作者 单位 E-mail
贾永芳
西南交通大学超导与新能源研究开发中心,材料先进技术教育部重点实验室,成都 610031;四川工程职业技术学院机电工程系,德阳 618000
yongfangj@126.com

蔡芳共
西南交通大学超导与新能源研究开发中心,材料先进技术教育部重点实验室,成都 610031;西部超导材料科技股份有限公司,西安710018
 
鲁双伟
西南交通大学超导与新能源研究开发中心,材料先进技术教育部重点实验室,成都 610031
 
杨峰
西南交通大学超导与新能源研究开发中心,材料先进技术教育部重点实验室,成都 610031
 
赵勇
西南交通大学超导与新能源研究开发中心,材料先进技术教育部重点实验室,成都 610031;新南威尔士大学材料科学与工程学院,悉尼 2052
 

中文摘要:
      双通TiO2纳米管阵列膜的成功制备可有效提高TiO2纳米管阵列膜的光催化活性,同时还可扩展其在太阳能电池、气体敏感器等方面的应用,具有很强的实际意义。在大量文献调研的基础上,综述了双通TiO2纳米管阵列膜的阳极氧化制备方法及其在催化与制氢、氢敏特性、分子过滤等方面的应用进展,并侧重讨论了双通TiO2纳米管阵列膜的分离机制。最后,对双通TiO2纳米管阵列膜的后续发展方向和应用前景进行了展望。
英文摘要:
      The preparation of through-hole TiO2 nanotube arrays has practical significance to enhance the photocatalytic activity of TNAs, as well as expanding their applications in solar cell,gas sensor and so on. Based on a large number of literatures, this paper reviews the preparation technology of through-hole TiO2 nanotube arrays membrane, as well as the application progress in hydrogen production, hydrogen sensing properties and molecular filtration, moreover, the separation mechanisms of the through-hole TiO2 nanotube arrays membrane are mainly discussed. Finally, the development and application prospects of TNAs are presented.

吴腾飞,敖燕辉,王沛芳,王超.碳量子点的合成和应用[J].材料导报,2016,30(13):30-35
碳量子点的合成和应用
Carbon Quantum Dots:Synthesis and Applications
 
DOI：10.11896/j.issn.1005-023X.2016.013.005

中文关键词: 碳量子点 合成 应用

英文关键词: CQDs, synthesis, applications

基金项目:国家自然科学基金委创新群体(51421006)；国家自然科学基金优秀青年基金(51422902)；国家自然科学基金重点基金(41430751)；国家自然科学基金面上项目(51479065)；江苏省自然科学基金面上项目(BK20141417)；教育部创新团队(IRT13061)；江苏高效优势学科建设工程资助项目
作者 单位 E-mail
吴腾飞
河海大学,浅水湖泊综合治理与资源开发教育部重点实验室,南京 210098
tfwu@hhu.edu.cn,hjxy@hhu.edu.cn

敖燕辉
河海大学,浅水湖泊综合治理与资源开发教育部重点实验室,南京 210098
tfwu@hhu.edu.cn,hjxy@hhu.edu.cn

王沛芳
河海大学,浅水湖泊综合治理与资源开发教育部重点实验室,南京 210098
 
王超
河海大学,浅水湖泊综合治理与资源开发教育部重点实验室,南京 210098
 

中文摘要:
      近几年,碳量子点作为纳米碳材料中的一颗新星,引起了人们广泛的关注。碳量子点除了具有优秀的光学性质,还有良好的水溶性、低毒性、环境友好、成本低等优点。自从碳量子点被发现以来,人们发现了多种多样的合成碳量子点的方法,主要有电化学法、化学烧蚀法、激光法和微波法等。由于碳量子点具有许多优点,被广泛应用于很多领域,特别是在光催化、生物成像、化学传感等方面。本文介绍了碳量子点的主要合成方法和主要应用。
英文摘要:
      Carbon quantum dots have attracted widespread attention as a rising star in nanocarbon in recent years. Since their discovery, people found many synthetic methods to derive carbon quantum dots, mainly including electrochemical, chemical, laser ablation and microwave. For their optical properties, water solubility, low toxicity, chemical inertness, low cost, CQDs have found many applications in many field, especially in catalysis, bioimaging, chemical sensing. Herein we describe the progress in the field of CQDs, focusing on their synthetic methods and applications.

郭治平,刘翔,潘顺臣,吴长树,陈清明,段云彪?.Hg1-xCdxSe红外薄膜材料研究进展[J].材料导报,2016,30(13):36-42
Hg1-xCdxSe红外薄膜材料研究进展
A Survey of Hg1-xCdxSe Materials Used for Infrared Detectors
 
DOI：10.11896/j.issn.1005-023X.2016.013.006

中文关键词: 硒镉汞 碲镉汞 长波红外 焦平面阵列

英文关键词: mercury cadmium selenide, mercury cadmium telluride, long-wavelength infrared, focal plane arrays

基金项目:国家自然科学基金(61367008)
作者 单位 E-mail
郭治平
昆明理工大学材料科学与工程学院,昆明650093
guo417777529@126.com

刘翔
昆明理工大学材料科学与工程学院,昆明650093
 
潘顺臣
昆明物理研究所,昆明 650223
 
吴长树
昆明物理研究所,昆明 650223
 
陈清明
昆明理工大学材料科学与工程学院,昆明650093
 
段云彪?
昆明理工大学材料科学与工程学院,昆明650093
 

中文摘要:
      硒镉汞(Hg1-xCdxSe)作为碲镉汞(Hg1-xCdxTe)的红外替代材料受到广泛关注,它具有位错密度低、热膨胀系数小、晶格失配小等优势,可望获得高质量、大面积、廉价长波红外(Long-wavelength infrared, LWIR)焦平面阵列(Focal plane arrays, FPAs)。综述了Hg1-xCdxSe材料的最新研究进展,讨论了Hg1-xCdxSe薄膜材料在不同衬底和不同生长条件下对薄膜质量的影响及最新研究结果；同时,对Hg1-xCdxSe材料的研究进行了展望。
英文摘要:
      As one alternative infrared (IR) material of mercury cadmium telluride (Hg1-xCdxTe), mercury cadmium selenide (Hg1-xCdxSe) has attracted extensive attention in the field of third generation IR materials. For some advantages of low dislocation density, low thermal expansion coefficient, low lattice mismatch and so on, Hg1-x-CdxSe material could be used to prepare high quality, large-area, and low-cost long-wavelength infrared (LWIR) focal plane arrays (FPAs). In this paper, the research progress of Hg1-xCdxSe IR materials is summarized, the influences of the different substrates and various growth conditions on the qualities of Hg1-xCdxSe films are discussed in details, and its future development is put in prospect as well.

周露露,汪竞阳,屈少华,罗中杰,钟志成,胡奥.水热法制备TiO2纳米棒阵列及应用研究进展[J].材料导报,2016,30(13):43-48, 75
水热法制备TiO2纳米棒阵列及应用研究进展
Progress on Hydrothermal Synthesis and Applications of TiO2 Nanorod Arrays
 
DOI：10.11896/j.issn.1005-023X.2016.013.007

中文关键词: TiO2纳米棒阵列 水热法 形貌优化 太阳能电池 光催化

英文关键词: TiO2 nanorod arrays, hydrothermal method, morphology optimization, solar cells, photocatalysis

基金项目:国家自然科学基金(51302075)；湖北省自然科学基金重点项目(ZRZ2015000203)
作者 单位 E-mail
周露露
湖北文理学院物理与电子工程学院,襄阳 441053;中国地质大学武汉数学与物理学院,武汉 430074
cugzll@163.com

汪竞阳
湖北文理学院物理与电子工程学院,襄阳 441053
cugzll@163.com

屈少华
湖北文理学院物理与电子工程学院,襄阳 441053
 
罗中杰
中国地质大学武汉数学与物理学院,武汉 430074
 
钟志成
湖北文理学院物理与电子工程学院,襄阳 441053
 
胡奥
湖北文理学院物理与电子工程学院,襄阳 441053
 

中文摘要:
      TiO2纳米棒阵列由于具有电子传输率高和光散射效应强等优异的特性,从而在太阳能电池、光催化、光解水制氢等领域中具有广阔的应用前景。主要从水热法制备工艺及生长机理、形貌优化及改性和应用几个方面综述了TiO2纳米棒阵列的研究进展,并对今后的研究趋势进行展望。
英文摘要:
      TiO2 nanorod arrays are widely applied in solar cells, photocatalysis, solar water splitting (for hydrogen production) because of their high electron mobility ratio and excellent light scattering effect. This paper provides a description on research progress of TiO2 nanotube arrays in terms of hydrothermal synthesis method and growth mechanism, morphology optimization, modification, as well as applications, followed by a brief prospect on the development trends.

周霞,汪会波,董建峰.超表面的电磁特性研究进展[J].材料导报,2016,30(13):49-54
超表面的电磁特性研究进展
Research Advances of Electromagnetic Properties of Metasurfaces
 
DOI：10.11896/j.issn.1005-023X.2016.013.008

中文关键词: 超表面 超材料 不对称传输 圆极化波 线极化波

英文关键词: metasurfaces, metamaterials, asymmetric transmission, circularly polarized wave, linearly pola-rized wave

基金项目:国家自然科学基金(61475079)
作者 单位 E-mail
周霞
宁波大学信息科学与工程学院,宁波 315211
 
汪会波
宁波大学信息科学与工程学院,宁波 315211
549754831@qq.com,1418439745@qq.com

董建峰
宁波大学信息科学与工程学院,宁波 315211
549754831@qq.com,1418439745@qq.com

中文摘要:
      超表面由于具有自然界不存在的独特电磁特性而引起了人们极大的兴趣,它是占有更少物理空间,提供更小损耗,更容易被制造的一类超材料。简要介绍了超表面的概念和背景,并着重阐述了超表面结构在微波段、太赫兹波段以及光频段的模拟计算及实验研究进展。这些超表面在微波、光波、光电子器件中具有潜在的应用价值。
英文摘要:
      Metasurfaces have attracted great attention due to its unique electromagnetic properties unseen in the natural world, and it is a kind of metamaterial which takes up less physical space, offers reduced losses and is easier to be fabricated. The concept and background of metasurfaces are briefly introduced. The research progress on simulations and experiments through metasurface structures in microwave, terahertz bands and optical frequencies are reviewed in detail, aiming to reveal these metasurfaces′potential applications in microwave, optical and photonic devices.

陈颖,邵高峰,吴晓栋,沈晓冬,崔升.聚合物气凝胶研究进展[J].材料导报,2016,30(13):55-62, 70
聚合物气凝胶研究进展
Advances in Polymer Aerogels
 
DOI：10.11896/j.issn.1005-023X.2016.013.009

中文关键词: 聚合物 气凝胶 结构 性能 应用

英文关键词: polymer, aerogel, structure, property, application

基金项目:长江学者和创新团队发展计划(1RT_15R35)；江苏省科技支撑计划(工业)项目(BE2014128)；航空科学基金(201452T4001)；江苏省高校自然科学研究重大项目(15KJA430005)；江苏省产学研前瞻性联合研究项目(BY2015005-01)；江苏先进无机功能复合材料协同创新中心；江苏高校优势学科建设工程 陈颖:1991年生,硕士生,主要研究方向为聚合物气凝胶材料 Tel:025-58139286 E-mail:18751902978@163.com 沈晓冬:通讯作者,1964年生,博士,教授,研究方向为纳米材料 Tel:025-83587235 E-mail:xdshen@njtech.edu.cn
作者 单位 E-mail
陈颖
南京工业大学材料科学与工程学院,材料化学国家重点实验室,南京210009
 
邵高峰
南京工业大学材料科学与工程学院,材料化学国家重点实验室,南京210009
 
吴晓栋
南京工业大学材料科学与工程学院,材料化学国家重点实验室,南京210009
 
沈晓冬
南京工业大学材料科学与工程学院,材料化学国家重点实验室,南京210009
18751902978@163.com

崔升
南京工业大学材料科学与工程学院,材料化学国家重点实验室,南京210009
 

中文摘要:
      气凝胶是经溶胶-凝胶过程结合一定的干燥方法制备得到的多孔纳米材料。聚合物气凝胶不仅具有聚合物材料的低介电常数、良好力学性能和灵活的分子设计性等特性,同时还具有无机气凝胶材料低密度、高孔隙率和低热导率等特点,被广泛应用于隔热、吸附和储能等领域。从合成、结构、性能和应用等方面介绍了聚氨酯(PU)、聚脲(PUA)、聚酰亚胺(PI)、聚苯并噁嗪(PBZ)和间规聚苯乙烯(sPS)类等常见聚合物气凝胶的研究进展,并对其未来的发展方向做出了展望。
英文摘要:
      Aerogels are the nanoporous materials consisting of hierarchical 3D assemblies of nanoparticles, which are derived from sol-gel process combined with drying methods. Recently, polymer aerogels have been consi-dered as a candidate material in various fields such as thermal insulation, adsorption, energy storage due to the unique characteristics, including ultra-low thermal conductivity, ultralight density, high porosity, low dielectric constant, excellent mechanical behavior and flexible molecular designing. This paper gives a comprehensive review about the recent progresses in preparation, structures, properties and applications of some common varieties of polymer aerogels, including polyurethane (PU), polyurea (PUA), polyimide (PI), polybenzoxazine (PBZ) and syndiotactic polystyrene (sPS) aerogels, as well as a brief prospect over the future research directions of this field.

解帅,冀志江,杨洋,王静.电磁波吸收建筑材料的应用研究进展[J].材料导报,2016,30(13):63-70
电磁波吸收建筑材料的应用研究进展
Recent Progress in Electromagnetic Wave Absorbing Building Materials
 
DOI：10.11896/j.issn.1005-023X.2016.013.010

中文关键词: 电磁波吸收 建筑材料 反射率

英文关键词: electromagnetic wave absorption, building material, reflectivity

基金项目:国家十二五科技支撑计划课题(2014BAB15B02-02)
作者 单位 E-mail
解帅
中国建筑材料科学研究总院,绿色建筑材料国家重点实验室,北京 100024;武汉理工大学材料科学与工程学院,武汉 430070
 
冀志江
中国建筑材料科学研究总院,绿色建筑材料国家重点实验室,北京 100024
xs5649@163.com

杨洋
中国建筑材料科学研究总院,绿色建筑材料国家重点实验室,北京 100024
 
王静
中国建筑材料科学研究总院,绿色建筑材料国家重点实验室,北京 100024
 

中文摘要:
      应用电磁波吸收建筑材料是改善建筑空间电磁环境的有效方法。随着电磁辐射污染日益严重,吸波建材已逐渐成为研究热点。综述了近几年吸波建材的研究方法与研究现状,将吸波建材归纳为吸波剂填充型和结构设计型两大类,并分别进行评述,提出了现有研究中存在的一些问题以及进一步的研究方向。“轻、薄、宽、强”仍然是吸波建材的发展方向,同时电磁波损耗机理还有待进一步研究。
英文摘要:
      Application of electromagnetic wave (EMW) absorbing building materials is an effective method to improve the electromagnetic environment of architectural space. And the EMW absorbing material has been a hot area of research in recent years, as the electromagnetic radiation pollution increasing seriously. The recent advances and research methods of EMW absorbing building materials are reviewed in this paper. The materials are summarized as two major categories:filling absorbing agent and structure design, and then the shortcoming of current studies and approaches for further researchers are suggested after the review. Design of the ideal absorbing building materials with the characteristics of low density, thin matching thickness, broad bandwidth and strong microwave wave absorption, is the main direction, and the mechanism of wave absorption should be researched in depth.

柳红东,胡忠利,阮海波.无机固体电解质Li7La3Zr2O12的制备及掺杂改性研究进展[J].材料导报,2016,30(13):71-75
无机固体电解质Li7La3Zr2O12的制备及掺杂改性研究进展
Technological Advances in Preparation and Doping Modification of Li7La3Zr2O12 as Inorganic Solid Electrolyte
 
DOI：10.11896/j.issn.1005-023X.2016.013.011

中文关键词: 无机固体电解质 Li7La3Zr2O12 锂离子电池

英文关键词: inorganic solid electrolyte, Li7La3Zr2O12, lithium-ion batteries

基金项目:国家自然科学基金(51502030)；中国博士后基金面上项目(2015M582499)；重庆市科委基础与前沿研究计划项目(cstc2015jcyjA90020)；重庆市教委科学技术研究项目(KJ1501101)；重庆市博士后特别资助(Xm2015064)；重庆文理学院引进人才项目(R2013CJ06)
作者 单位 E-mail
柳红东
重庆文理学院新材料技术研究院,重庆 402160
lhd0415@126.com

胡忠利
重庆文理学院新材料技术研究院,重庆 402160
 
阮海波
重庆文理学院新材料技术研究院,重庆 402160
lhd0415@126.com

中文摘要:
      无机固体电解质由于其安全性能高、能量密度大等特点备受研究者的青睐。其中Garnet型锂离子无机固体电解质Li7La3Zr2O12具有较高的离子导电率,较低的界面电阻,优良的稳定性能和电化学性能,在未来的全固态锂离子电池、锂空气电池等领域有着广阔的应用前景。主要从Li7La3Zr2O12的晶体结构、制备工艺和掺杂改性等方面详细阐述无机固态电解质Li7La3Zr2O12的研究进展。
英文摘要:
      Inorganic solid electrolytes have attracted considerable attention because of its high safety perfor-mance and energy density, among which Li7La3Zr2O12 with garnet-structure exhibits high ionic conductivity, low interface resistance, excellent stability and electrochemical properties, as well as broad application prospects such as all-solid-state lithium-ion batteries and lithium-air batteries. In this review, the research progress of Li7La3Zr2O12 is surveyed in terms of its crystal structures, preparation and doping modification technologies.

陈思艮,祝琳华,何艳萍,司甜.钒基催化剂上丙烷氧化脱氢催化性能研究进展[J].材料导报,2016,30(13):76-80, 86
钒基催化剂上丙烷氧化脱氢催化性能研究进展
Research Progress on the Catalytic Performance of Supported Vanadium-base Catalysts for Oxidative Dehydrogenation of Propane
 
DOI：10.11896/j.issn.1005-023X.2016.013.012

中文关键词: 丙烷氧化脱氢 丙烯 钒基催化剂

英文关键词: oxidative dehydrogenation of propane, propylene, vanadium-base catalyst

基金项目:国家自然科学基金(20866004)
作者 单位 E-mail
陈思艮
昆明理工大学化学工程学院,昆明 650500
chensigenlt@163.com

祝琳华
昆明理工大学化学工程学院,昆明 650500
chensigenlt@163.com

何艳萍
昆明理工大学化学工程学院,昆明 650500
 
司甜
昆明理工大学化学工程学院,昆明 650500
 

中文摘要:
      低碳烷烃作为一种资源丰富且廉价的原料,利用其可制取具有高附加值的烯烃和含氧衍生物,对缓解丙烯和石油资源短缺具有重要的价值。但丙烷在高温下易深度氧化和深度裂解,且催化剂易积碳失活,使得丙烯选择性降低,故迫切需要开发低温高效的催化剂。简要介绍了丙烷氧化脱氢制丙烯的研究意义和钒基催化剂上丙烷氧化脱氢反应的机理,综述了负载型钒基催化剂的载体类型及性质、活性物种引入方式、表面钒物种的还原性能、钒负载量、氧化剂的选择对丙烷氧化脱氢催化活性及对丙烯选择性的影响。
英文摘要:
      Light alkanes is a cheap chemical material with abundant reserve in the world. Acquisition of olefins and oxy-compounds with high additive value as propylene from propane always attracts extensive attention in industry field, because the study of oxidative dehydrogenation of propane to propylene products has mitigated the propylene and oil resources shortage. However, high temperature not only easily induces serious overoxidation and pyrolysis of propane but also generates catalyst coke. Hence, the development of new catalysts with superior activity at low temperatures becomes the research focus in this field. In this paper, the research significance and the vanadium-base catalysts mechanism for the dehydrogenation of propane to propylene are briefly introduced. Moreover, some influence factors on catalytic performance of supported V-base catalysts for oxidative dehydrogenation (ODH) of propane process, such as properties of support material, routes of introducing active species, redox properties, vanadium loading and oxidant selection etc are analyzed in detail.

罗文峰,杨雪香,敖宁建.生物医用材料的3D打印技术与发展[J].材料导报,2016,30(13):81-86
生物医用材料的3D打印技术与发展
A Review of Three Dimensional Printing Technologies for Biomaterial Applications
 
DOI：10.11896/j.issn.1005-023X.2016.013.013

中文关键词: 3D打印技术 生物医用材料 组织工程

英文关键词: 3D printing technology, biomaterials, tissue engineering

基金项目:国家自然科学基金(209760868/B060805)
作者 单位 E-mail
罗文峰
暨南大学生物医学工程系, 广州510632;广东省教育厅生物材料重点实验室, 广州510632
540995477@qq.com

杨雪香
暨南大学生物医学工程系, 广州510632
 
敖宁建
暨南大学生物医学工程系, 广州510632;广东省教育厅生物材料重点实验室, 广州510632
540995477@qq.com

中文摘要:
      近年来,由于3D打印技术的迅猛发展,有关3D打印技术的应用受到科学界广泛关注,特别是生物医学领域。3D打印材料的瓶颈制约着3D打印技术的发展,特别是用于生物医学领域的打印材料,只有非常局限的几种,但是研究可打印生物医用材料意义重大,经济效益显著。简述了3D打印技术在生物医学工程上的应用。重点综述了用于3D打印的生物医用材料,主要涉及金属、陶瓷、高聚物、复合材料以及生物墨水等,并且阐述了3D打印材料的发展前景。
英文摘要:
      In recent years, due to the rapid development of 3D printing technologies, their application has acquired extensive interests, especially in the biomedical field. Materials are one of the bottleneck problems that troubled the development of 3D printing, especially in biomaterials. There are only a few biomaterials available for printing, but developing more printable biomaterials is significant and expected to generate remarkable economic benefits. This paper briefly presents the applications of 3D printing technology in biomedical engineering, followed by a vivid description about 3D printable biomaterials including metals, ceramics, polymers, composites and bioink. Besides, the prospect for 3D printing biomaterials is also mentioned.

王宇宙,董建新.汽车发动机用气门材料的选择及研究进展[J].材料导报,2016,30(13):87-93, 101
汽车发动机用气门材料的选择及研究进展
Review on the Selection and Research of Valve Materials Used in Automobile Engines
 
DOI：10.11896/j.issn.1005-023X.2016.013.014

中文关键词: 发动机气门 服役工况 材料选择 制备 失效

英文关键词: engine valve, service condition, material selection, preparation, failure

基金项目:
作者 单位 E-mail
王宇宙
北京科技大学材料科学与工程学院,北京 100083
universewang1990@126.com

董建新
北京科技大学材料科学与工程学院,北京 100083
universewang1990@126.com

中文摘要:
      首先概述了气门在汽车发动机中的重要作用,叙述了气门的服役工况以及对气门材料性能的要求,接着详细阐述了气门上常用的材料种类以及气门材料的国内外研究进展,然后对气门的整个制备流程进行了叙述,最后简述了气门使用过程中的失效问题。
英文摘要:
      This review firstly summarizes the important role of valve in automobile engines, and the service conditions of the valve and the corresponding performance requirements. After that, the commonly used valve mate-rials and the domestic and international research progress are expounded in detail. Finally, the whole preparation process of the valve is described attached with a brief introduction of valve failure.

井致远,许一,张伟,尹艳丽.有机钼作为润滑油添加剂的研究发展现状[J].材料导报,2016,30(13):94-101
有机钼作为润滑油添加剂的研究发展现状
Research Progress of Organic Molybdenum as Lubricating Additive
 
DOI：10.11896/j.issn.1005-023X.2016.013.015

中文关键词: 有机钼 润滑油添加剂 摩擦学性能

英文关键词: organic Mo, lubricating oil additive, tribological property

基金项目:军内科研资助项目(ZS201570131)
作者 单位 E-mail
井致远
装甲兵工程学院装备再制造技术国防科技重点实验室,北京 100072
jing_zhiyuan@163.com

许一
装甲兵工程学院装备再制造技术国防科技重点实验室,北京 100072
 
张伟
装甲兵工程学院装备再制造技术国防科技重点实验室,北京 100072
 
尹艳丽
装甲兵工程学院装备再制造技术国防科技重点实验室,北京 100072
 

中文摘要:
      有机钼是一种具有优良减摩抗磨效果的润滑油添加剂。随着人们对油品质量要求的提高以及新的润滑油质量标准的提出,有机钼添加剂也在不断地朝低磷硫、无污染的方向发展。综述了有机钼添加剂的研究发展现状,对有机钼润滑添加剂根据是否含有硫、磷元素进行了分类介绍。根据种类的不同阐述了有机钼的润滑机理,并总结了影响不同种类有机钼摩擦学性能的影响因素和复配的研究情况,最后提出了有机钼研究中仍存在的一些问题。
英文摘要:
      Organic Mo is a kind of lubricating oil additive. With the improvement of the requirement to the lubricant quality and the proposal of the new standard to the lubricant quality, organic Mo additive is developing towards low sulfur and phosphor or pollution. The research progress of organic Mo lubricating additive is summarized, and organic Mo lubricating additive is introduced in classification according to whether it contains sulfur and phosphor. The mechanism of organic Mo is expounded. Factors affecting the tribological properties of different kinds of organic Mo and research of their compounding are concluded. Some problems remaining in the research of organic Mo are put forward.

刘岩,王凯,王建明,贺春林.大线能量焊接条件下低合金高强度钢针状铁素体形核影响因素及形核机理研究[J].材料导报,2016,30(13):102-105, 118
大线能量焊接条件下低合金高强度钢针状铁素体形核影响因素及形核机理研究
Acicular Ferrite Nucleation in High Strength Low Alloys Steel During High Heat Input Welding:Influences and Mechanism
 
DOI：10.11896/j.issn.1005-023X.2016.013.016

中文关键词: 大线能量焊接 低合金高强度钢 针状铁素体 力学性能 形核机理

英文关键词: high heat input welding,high strength low alloys steel,intragranular ferrite,mechanical property,nucleation mechanism

基金项目:辽宁省自然科学基金优秀人才培育专题(2014020097)；辽宁省高校科研项目(L2014475) 刘岩:博士,副教授,研究方向为金属材料 E-mail:liuyanneu@163.com
作者 单位
刘岩
沈阳大学辽宁省先进材料制备技术重点实验室,沈阳 110044

王凯
沈阳大学辽宁省先进材料制备技术重点实验室,沈阳 110044

王建明
沈阳大学机械工程学院,沈阳 110044

贺春林
沈阳大学辽宁省先进材料制备技术重点实验室,沈阳 110044

中文摘要:
      综述了大线能量焊接条件下低合金高强度钢中针状铁素体形成的研究进展,概述了针状铁素体显微组织结构特点及其在低合金高强度钢中的主要性能,具体讨论了针状铁素体具有良好强韧性和抗断裂性等力学性能的原因,重点分析了大线能量焊接条件下影响焊接热影响区中针状铁素体形核长大的因素,包括合金元素及夹杂物的种类和尺寸,得出针状铁素体的形核机理是多种机理联合作用的结果。
英文摘要:
      The research progress of the formation of intragranular ferrite in high strength low alloy steel is summarized. The microstructure characteristics of intragranular ferrite and its main properties in high strength low alloy steel are generalized. The reasons for the mechanical properties of intragranular ferrite with good toughness and fracture resistance are discussed. The factors that affect the nucleation and growth of the intragranular ferrite such as alloy elements and types and sizes of inclusions in welding heat affected zone are analyzed. Multiple mechanisms combining of acicular ferrite nucleation mechanism is obtained.

崔令江,林熙原,朱强,王传杰,张鹏.高温合金热处理工艺研究进展[J].材料导报,2016,30(13):106-110, 132
高温合金热处理工艺研究进展
Research Progress on Heat Treatment Process of Superalloys
 
DOI：10.11896/j.issn.1005-023X.2016.013.017

中文关键词: 高温合金 热处理 组织 性能

英文关键词: superalloy, heat treatment, organization, performance

基金项目:国家自然科学基金(51575129)
作者 单位
崔令江
哈尔滨工业大学威海材料科学与工程学院,威海 264209

林熙原
哈尔滨工业大学威海材料科学与工程学院,威海 264209

朱强
哈尔滨工业大学威海材料科学与工程学院,威海 264209

王传杰
哈尔滨工业大学威海材料科学与工程学院,威海 264209

张鹏
哈尔滨工业大学威海材料科学与工程学院,威海 264209

中文摘要:
      高温合金是一类在高温及一定应力条件下长期工作的高温金属材料,具有良好的综合性能,被广泛地应用于航空航天等领域。适当的热处理工艺通过改变合金的微观组织来提升其性能。总结了近几年高温合金热处理工艺的研究进展,详细论述了变形高温合金、铸造高温合金和粉末高温合金的热处理工艺及热处理对其组织和性能的影响,并阐述了高温合金热处理工艺的发展趋势。
英文摘要:
      Superalloy, a kind of high-temperature metallic materials under the service conditions of high temperature and certain stress for long time, possesses a perfect overall performance, which is widely used in aerospace and other fields. Appropriate heat treatment process can improve alloy performance by changing its microstructure. The research progress of superalloy heat treatment process in recent years is summarized. Heat treatment process of the deformation superalloy, casting superalloy, powder superalloy and effect of heat treatment on their organization and performance are discussed in detail. The development trend of superalloy heat treatment process is described.

凌礼恭,王徐颖,陆永浩,丁贤飞,初起宝.压水堆控制棒驱动机构CANOPY密封焊缝服役环境与失效[J].材料导报,2016,30(13):111-118
压水堆控制棒驱动机构CANOPY密封焊缝服役环境与失效
The Service Environment and Failure of the CANOPY Seal Weld on the Control Rod Drive Mechanism in PWR
 
DOI：10.11896/j.issn.1005-023X.2016.013.018

中文关键词: CANOPY密封焊缝 溶解氧 氯 应力腐蚀开裂 点蚀 穿晶应力腐蚀 沿晶应力腐蚀

英文关键词: CANOPY seal welds, dissolved oxygen, chlorine, stress corrosion crack, pitting, transgranular stress corrosion cracking, intergranular stress corrosion crack

基金项目:
作者 单位 E-mail
凌礼恭
北京科技大学国家材料服役安全科学中心,北京 100083;环境保护部核与辐射安全中心,北京 100088
lingligong2008@163.com

王徐颖
北京科技大学国家材料服役安全科学中心,北京 100083
 
陆永浩
北京科技大学国家材料服役安全科学中心,北京 100083
lingligong2008@163.com

丁贤飞
北京科技大学国家材料服役安全科学中心,北京 100083
 
初起宝
环境保护部核与辐射安全中心,北京 100088
 

中文摘要:
      综述了国际上对PWR核电站控制棒驱动机构密封焊缝(CSWs)结构、载荷、应力状态、失效分析的研究。研究认为CSWs的结构设计易造成高溶解氧服役环境,在CSWs死水区空腔存在微量氯离子污染的可能,导致较大应力腐蚀倾向。目前研究确认的失效模式有穿晶应力腐蚀(TGSCC)、沿晶应力腐蚀(IGSCC)、SCC+点蚀。计算出CSWs死水区空腔理论浓度可达230×10?-6,分析认为溶解氧和低浓度水平的氯污染是可引起上述腐蚀的环境因素；CSWs应力腐蚀裂纹扩展模式与材料敏化、服役溶液环境、初始应变、应力状态等因素相关；点蚀可能成为应力腐蚀的起源也可发展成为独立的破坏形式。
英文摘要:
      The international research status of the structure, load, stress state and failure analysis of the CANOPY seal welds (CSWs), which are belong to the control rod drive mechanism (CRDM) in PWR nuclear power plant, are reviewed in detail. Research shows that CSWs backwater cavity is easy to form high dissolved oxygen (DO) and chloride ion contamination possibly exist under service environment, which both lead to high susceptibility of stress corrosion crack(SCC). The failure modes of CSWs confirmed by previous research are among transgranular stress corrosion cracking(TGSCC), intergranular stress corrosion crack(IGSCC),and SCC+pitting. We calculate the theoretical concentration of CSWs backwater cavity which is up to 230×10?-6, and conclude that the DO and chlorine pollution are the environmental factors that can cause the above corrosion modes. The review also suggested that the crack growth mode of CSWs′ stress corrosion depends on sensitization of material, service solution environment, initial strain, stress state and so on. In addition, pitting may become crack origin of SCC or evolves into independent damage as well.

王鹤,李芬,张彦平,王新,李梁,王奇飞.污水厂剩余污泥材料化和能源利用技术研究进展[J].材料导报,2016,30(13):119-124
污水厂剩余污泥材料化和能源利用技术研究进展
Research Progress in Materialization and Energy Utilization of the Surplus Sludge of Sewage Treatment
 
DOI：10.11896/j.issn.1005-023X.2016.013.019

中文关键词: 剩余污泥 材料化 能源化

英文关键词: surplus sludge, materialization, energy utilization

基金项目:哈尔滨市科技创新人才研究专项资金(2014RFQXJ056)；河北省自然科学基金(E2015202345)；绿色化工技术黑龙江省高等学校科技创新团队(2014TD007)
作者 单位
王鹤
哈尔滨理工大学化学与环境工程学院,哈尔滨 150040

李芬
哈尔滨理工大学化学与环境工程学院,哈尔滨 150040

张彦平
河北工业大学土木工程学院,天津 300401

王新
中国昆仑工程公司,北京 100037

李梁
哈尔滨理工大学化学与环境工程学院,哈尔滨 150040

王奇飞
哈尔滨理工大学化学与环境工程学院,哈尔滨 150040

中文摘要:
      剩余污泥为污水处理厂副产物,具有成分复杂难处理,易滋生二次污染的特性。主要介绍了近年来剩余污泥制吸附剂和能源化技术的研究进展。由于剩余污泥中有机质含量丰富,首先对单一污泥和剩余污泥添加工农业废弃物制备吸附剂的研究现状进行了介绍,指出吸附材料制备过程中活化剂大量使用会造成环境的再污染；随后综述了剩余污泥直接能源化,或通过热解等手段将其间接能源化的研究进展；最后提出用生物质废弃物代替化学活化剂制备污泥吸附剂的研究思路,并指出将污泥制备材料和能源利用技术相结合是今后剩余污泥资源化研究的主要发展方向。
英文摘要:
      Excess sludge is the byproduct of the sewage treatment plant, which has the complex composition, difficult to dispose of, and could easily breed secondary pollutants characteristics. This paper mainly describes the research progress of using excess sludge for sorbent manufacturing and energy utilization technology in recent years. Since excess sludge is rich in organic matter, the paper will first introduce the research status on absorbent manufacturing from single sludge and excess sludge in combination with agricultural and industrial waste, and it will cause the recontamination of environment due to extensive use of activating agents in the absorbent manufacturing process. Then the paper will go on to summarize the research progress of excess sludge in direct energy utilization, or indirect energy utilization by means of pyrogenic decomposition. In the end, we propose the idea that using biomass waste take the place of chemical activating agents in preparation of sludge absorbents. And it is indicated that the combination of sludge materialization and energy utilization technology will become the mainstream direction in excess sludge resources.

陈鑫,李龙,周德敬.铝钢金属间化合物生长及其抑制机理的研究现状[J].材料导报,2016,30(13):125-132
铝钢金属间化合物生长及其抑制机理的研究现状
Review on the Formation and Inhibition Mechanism of Fe-Al Intermetallic Compound
 
DOI：10.11896/j.issn.1005-023X.2016.013.020

中文关键词: 铝钢金属间化合物 生成顺序 抑制机理 不同合金元素 Si

英文关键词: Fe-Al intermetallic compound, formation subsequence, inhibition mechanism, different alloy element, Si

基金项目:国家高技术研究发展计划资助项目(2013AA031301)；国家国际科技合作专项项目(2013DFB50170)；江苏省重点实验室资助项目(BM2014006)
作者 单位
陈鑫
银邦金属复合材料股份有限公司,江苏省金属层状复合材料重点实验室,无锡 214145

李龙
银邦金属复合材料股份有限公司,江苏省金属层状复合材料重点实验室,无锡 214145

周德敬
银邦金属复合材料股份有限公司,江苏省金属层状复合材料重点实验室,无锡 214145

中文摘要:
      铝钢复合材料兼具钢良好的力学性能和铝的耐腐蚀、高导热性、密度低等特点,可以满足许多特殊使用要求。铝钢界面若生成金属间化合物,会破坏铝钢基体间的冶金结合,严重影响材料的使用性能。因此,抑制铝钢界面金属间化合物的生长是开发铝钢复合材料的关键。对铝钢金属间化合物的生长及其抑制机理进行了较为系统的综述,介绍了铝钢界面常见的金属间化合物生成相的种类、晶体结构,从热力学与动力学角度对金属间化合物的生成机理及形成顺序进行了阐述。此外,对比总结了不同合金元素对铝钢金属间化合物形成的影响规律,着重分析了Si元素对铝钢金属间化合物生长的抑制机理。
英文摘要:
      Al-steel clad material has been widely used due to its excellent performance both with good mechanical property of steel and corrosion resistance, high thermal conductivity, low density of Al.The metallurgical bonding between the Al and the steel will be damaged when the intermetallic compound generated in the interface.It seriously deteriorates the performance of the material.So it′s important to inhibit the growth of the intermetallic compound for develop the Al-steel clad material.This paper summarizes the formation and inhibition mechanism of Fe-Al intermetallic compound.Introduce the type and crystal structure of the most common Fe-Al intermetallic compound phases.Discuss the mechanism and the subsequence on the formation of the intermetallic compound from the aspects of thermodynamics and dynamics.Then compare the effect of different alloy element on the formation of the Fe-Al intermetallic compound.Especially,the inhibition mechanism of Si on the formation of Fe-Al intermetallic compound is emphatically considered.

李春景,孙振平,李奇,罗琼.低场核磁共振技术在水泥基材料中的应用[J].材料导报,2016,30(13):133-138
低场核磁共振技术在水泥基材料中的应用
Application of Low-field Nuclear Magnetic Resonance in Cement-based Materials
 
DOI：10.11896/j.issn.1005-023X.2016.013.021

中文关键词: 核磁共振 水化 孔结构 扩散系数

英文关键词: nuclear magnetic resonance(NMR), hydration, pore structure, diffusion coefficient

基金项目:?? 国家自然科学基金(51178339)
作者 单位 E-mail
李春景
同济大学先进土木工程材料教育部重点实验室,上海 201804
15317083581@163.com

孙振平
同济大学先进土木工程材料教育部重点实验室,上海 201804
15317083581@163.com

李奇
上海东大化学有限公司,上海 201508
 
罗琼
上海东大化学有限公司,上海 201508
 

中文摘要:
      近年来,核磁共振技术已经成为表征水泥基材料水化进程、非化学结合水量和孔结构的一种重要手段。简单介绍了核磁共振基本原理和低场核磁共振主要参数；阐述了低场核磁共振技术在水泥基材料测试中的应用,主要包括水化进程、孔结构、水分迁移和扩散等方面的内容；展望了低场核磁共振技术在水泥基材料研究中的应用前景。
英文摘要:
      In recent years, nuclear magnetic resonance has become an important technique for characterizing hydration process, non-chemical bound water and pore structure of cement-based materials. This paper briefly introduces fundamentals of nuclear magnetic resonance and several main parameters about low-field nuclear magnetic resonance, lists the application of low-field nuclear magnetic resonance in cement-based materials, which include hydration process, pore structure, moisture migration and diffusion et al., and provide an outlook on the development trend and prospects of the low-field magnetic resonance applied in cement-based materials.

宋强,张琼,李婷.氧化镁对高镁熟料膨胀和强度影响研究进展[J].材料导报,2016,30(13):139-144, 158
氧化镁对高镁熟料膨胀和强度影响研究进展
Effect of Magnesia on Expansion and Strength in High-magnesium Clinker:A Short Review
 
DOI：10.11896/j.issn.1005-023X.2016.013.022

中文关键词: 高镁熟料 方镁石 膨胀 强度

英文关键词: high-magnesium clinker, periclase, expansion, strength

基金项目:国家重点基础研究发展(973)计划(2012CB723302);陕西省自然科学基金(2012JM6006)
作者 单位
宋强
西安建筑科技大学材料与矿资学院,西安 710055

张琼
西安建筑科技大学材料与矿资学院,西安 710055

李婷
西安建筑科技大学材料与矿资学院,西安 710055

中文摘要:
      从石灰石资源高效利用、高镁水泥补偿混凝土收缩方面阐述了高镁熟料生产的意义。针对高镁熟料中内含MgO,从方镁石膨胀影响因素、生料组成和煅烧制度对方镁石含量的影响,以及MgO对水泥熟料矿物相含量和强度的影响等方面,详细讨论了近年来国内外研究进展,对存在的有关问题进行了讨论,并提出了进一步研究建议。
英文摘要:
      The significance of high magnesium clinker production is discussed from the viewpoint of efficient utilization of limestone resources and advantage of compensation effect of high magnesium cement for concrete shrin-kage. Recent development on factors influencing periclase expansion,effects of raw material composition and burning condition on the content of periclase, and mineral content and strength development of high MgO clinker are reviewed. The existing problems are discussed, and the further research aspects are proposed.

潘崇根,李伊伊,舒咚咚,王锃,祝少杰,毛江鸿,金伟良.迁移型阻锈剂在钢筋混凝土中的研究进展[J].材料导报,2016,30(13):145-151
迁移型阻锈剂在钢筋混凝土中的研究进展
Development of Migrating Corrosion Inhibitor in Reinforced Concrete
 
DOI：10.11896/j.issn.1005-023X.2016.013.023

中文关键词: 迁移型阻锈剂 氯离子 阳离子型 耐久性

英文关键词: migrating corrosion inhibitor, chloride ion, cationic, durability

基金项目:国家自然科学基金(51541904;51408544);浙江省自然科学基金(LY16E090007);宁波市科技创新团队项目(2011B81005);浙江省公益基金(2015C31033)
作者 单位 E-mail
潘崇根
浙江大学宁波理工学院土木建筑工程学院,宁波 315100;浙江大学建筑工程学院,杭州 310058
panchonggen@zju.edu.cn

李伊伊
浙江大学宁波理工学院土木建筑工程学院,宁波 315100
 
舒咚咚
浙江大学宁波理工学院土木建筑工程学院,宁波 315100
 
王锃
浙江大学宁波理工学院土木建筑工程学院,宁波 315100
 
祝少杰
浙江大学宁波理工学院土木建筑工程学院,宁波 315100
 
毛江鸿
浙江大学宁波理工学院土木建筑工程学院,宁波 315100
 
金伟良
浙江大学宁波理工学院土木建筑工程学院,宁波 315100;浙江大学建筑工程学院,杭州 310058
 

中文摘要:
      钢筋锈蚀导致混凝土耐久性的降低问题一直受到全世界的广泛关注,迁移型有机阻锈剂可以有效提升混凝土的耐久性,并与混凝土结构有着很好的相容性,且在经济上优于普通掺入型无机阻锈剂。从混凝土工程钢筋锈蚀原因、迁移型阻锈剂的阻锈机理进行分析,进而介绍迁移型阻锈剂的国内外研究情况以及迁移型阻锈剂的性能试验和评价方法,最后就迁移型阻锈剂相关应用的问题进行总结。
英文摘要:
      Steel bar corrotion-induced durability degradation has received extensive attention from all over the world. Migrating corrosion inhibitor can improve the durability of concrete effectively, and it′s well compatible with structure of concrete. The economy of migrating corrosion inhibitor is also superior than inorganic corrosion inhibitor. In this paper, the corrosion reason of concrete and mechanism of migrating corrosion inhibitor are analyzed. Subsequently, domestic and foreign developments of migrating corrosion inhibitor are introduced, also with the property testing and evaluation method of migrating corrosion inhibitor. Finally, Application problems of migrating corrosion inhibitor are summarized.

陶祥令,刘辉,程雷.植被生态混凝土制备工艺研究进展[J].材料导报,2016,30(13):152-158
植被生态混凝土制备工艺研究进展
Research Status of Preparation Process for Vegetation Ecological Concrete
 
DOI：10.11896/j.issn.1005-023X.2016.013.024

中文关键词: 植被生态混凝土 制备工艺 评价指标 检测方法

英文关键词: vegetation ecological concrete, preparation process, evaluation index, test method

基金项目:住建部科技计划项目(2015-K4-015)；江苏省住建厅科技计划项目(2015ZD03；2015ZD21)；徐州市科技计划项目(KC14GX135；KC15SM027)；江苏建筑节能与建造技术协同创新中心开放基金(SJXTQ1507)
作者 单位 E-mail
陶祥令
江苏建筑职业技术学院能源与交通工程学院,徐州 221116;江苏建筑节能与建造技术协同创新中心,徐州 221116;中国矿业大学深部岩土力学与地下工程国家重点实验室,徐州 221116
chinatxl@126.com

刘辉
江苏建筑职业技术学院能源与交通工程学院,徐州 221116;江苏建筑节能与建造技术协同创新中心,徐州 221116
 
程雷
中国矿业大学深部岩土力学与地下工程国家重点实验室,徐州 221116
 

中文摘要:
      介绍了植被生态混凝土的定义及分类,以及这类混凝土的应用现状；通过总结前人针对制备方法的研究成果,包括配比设计、搅拌、成型、养护等步骤,提出了各个工艺需要掌握的关键因素；阐述了定量化衡量植被生态混凝土制备性能指标,并基于此性能指标讨论了影响因素与检测方法；阐明了植被型生态混凝土今后的发展方向。
英文摘要:
      The definition and classification of vegetation ecological concrete were introduced at first, and also its current situation of application. Then, according to the summary of previous studies on preparation methods, including the proportioning design, mixing, molding and curing method, the key factors of each process needed to be mastered were presented. After that, the evaluation index which could quantitative measure the performance of vegetation ecological concrete was proposed, and the influencing factors and the test method based on that were discussed. At last, the future development direction of vegetation ecological concrete was pointed out.